Hope this helps...
Hydrocarbons:
Measured in PPM (parts per million), this is the result of unburned fuel making it out the tailpipe. This failure is usually caused by an ignition (misfire), or an engine problem such as a bad valve. An engine running too lean will often have excessive HC due to what is called a "lean misfire". Any leaks in the intake system or bad injectors will also cause excessive HC due to uneven fuel distribution.
Failed the HC!
Check the ignition system first. This usually caused by an ignition miss. Then check the engine. Poorly seated valves, leaking head gaskets, or other compression problems will put the HC readings through the roof. Also check for vacuum leaks and the injector spray patterns. Remember, HC failures are usually caused by compression or ignition problems. Improper fuel distribution/vacuum leaks will cause misfires that will cause excessive HC.