A three angle valve job vs. a standard valve job wont have any effect on compression,the benefit is the flow around the seat of the valve. I haven't seen any specific flow data pertaining to the 4g63,but on V8s and such,a noticeable flow increase is seen with a multi angle valve job.
Although, I think what your mechanic is recommending is having the valves/seats resurfaced rather than just lapping and reinstalling. A lot of folks have luck with just lapping and reinstalling,but having a valve job done,pressure tested,and resurfaced is a good idea especially if you don't know the history of the head.
A multi angle valve job is pretty much standard with a performance valve job,and even standard valve jobs these days. Some of the newer machines actually machine the seats and valves rather than grind,and already incorporate three angles standard.